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Pyrylium-Mediated Synthesis ofN-(Benzyloxy)pyridinium Salts

✍ Scribed by Balaban, Teodor Silviu ;Tâmâşan, Iuliana ;Deleanu, Câlin


Book ID
102368511
Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
290 KB
Volume
1992
Category
Article
ISSN
0947-3440

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✦ Synopsis


Abstract

Pyrylium salts 3 react with (benzyloxy)amines 2 generated by hydrazinolysis from their N‐(benzyloxy)phthalimides to afford in moderate (35–65%) yields the corresponding title salts 4. The ^13^C‐ and ^1^H‐NMR spectra of the latter compounds are reported.


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Diphenyl-4-(5-R-2-furyl)pyrylium and 2,4-diphenyl-6-(5-bromo-2-furyl)pyrylium perchlorates and the corresponding pyridines and l-methylpyridinium perchlorates were synthesized. On the basis of the UV and PMR spectra it was concluded that there is significant electronic interaction of the furylium s