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Pyrroles from ketoximes and acetylene

✍ Scribed by B. A. Trofimov; A. I. Mikhaleva; A. N. Vasil'ev; M. V. Sigalov

Book ID: 112380273
Publisher: Springer US
Year: 1978
Tongue: English
Weight: 527 KB
Volume: 14
Category: Article
ISSN: 0009-3122
DOI: 10.1007/bf00635940

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The respective 2-aryl-and N-vinyl-2-arylpyrroles were obtained by the reaction of the oximes of alkyl aryl ketones with acetylene in the superbasic medium MOIl (M = Li, K)--DMSO. Their yields' depended largely on the structure of the ketoximes and on the reaction conditions. The Trofimov reaction a