The bitumen from the Whiterocks oil sand deposit in the Uinta Basin of eastern Utah was hydrotreated in a fixed-bed reactor to determine the extent of upgrading as a function of operating variables, including pressure (11.2-16.7 MPa), temperature (642-712 K) and liquid hourly space velocity (0.18-0.
Pyrolysis of oil sand from the Whiterocks deposit in a rotary kiln
โ Scribed by Francis V. Hanson; Soon-Man Cha; Milind D. Deo; Alex G. Oblad
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 928 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0016-2361
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โฆ Synopsis
A rotary kiln reactor was evaluated for thermal recovery of oil from Utah oil sands. A series of continuous-flow pyrolysis experiments was conducted. Process variables investigated included temperature (748-848 K), solids retention time ( 10 27 min ) and sweep gas flow rate ( 1.27-2.83 rn? h-' ). The results indicated that the pyrolysis temperature and the solids retention time were the two most important variables affecting the liquid and gas yields. The liquid yield (Cc ) decreased and the gas yield (C,-C,) increased with increasing temperature. The liquid yield increased with decreasing solids retention time, while the gas yield decreased. No significant effect of the sweep gas flow rate on the product distribution and yields was observed. The quality of the bitumen-derived liquids was significantly better than that of the bitumen. A preliminary process kinetics model which conforms to the observed trends was proposed.
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