Asymmetric diels-alder reactions of acry
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Wolfgang Oppolzer; Christian Chapuis
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Article
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1984
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Elsevier Science
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French
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Starting from (+)-camphor the chiral alcohols 1 and 8 have been prepared; their acrylates 9 and 13 underwent TiC12(0iPr) -mediated Diels-Alder additions to cyclopentadiene zth stereoface-differen 3, iations of 66% d.e. and 94% d.e., respectively.