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Asymmetric diels-alder reactions of acrylates derived from 3-alkyl-borneols and -isoborneols

✍ Scribed by Wolfgang Oppolzer; Christian Chapuis

Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 177 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)91290-0

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✦ Synopsis

Starting from (+)-camphor the chiral alcohols 1 and 8 have been prepared; their acrylates 9 and 13 underwent TiC12(0iPr)

-mediated Diels-Alder additions to cyclopentadiene zth stereoface-differen 3, iations of 66% d.e. and 94% d.e., respectively.

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