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Pyrolysis of CH2ClCH3: Considerations about its molecular nature

โœ Scribed by G. Huybrechts; Y. Hubin; B. Van Mele

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
367 KB
Volume
24
Category
Article
ISSN
0538-8066

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โœฆ Synopsis

Numerical integrations of a hypothetical radical chain reaction model have been performed for the pyrolysis of CHzClCH3 which is known to be molecular. Analyses of the modelling results have led to a better understanding of the participation (or nonparticipation) of "dead" radicals in the self-inhibition of the radical chain reaction. Attention is focused on the fact that apparently slow elementary reactions still may have to be taken into account in a pyrolysis mechanism when they produce "dead" radicals which can accumulate.

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Pyrolysis of 1-chloro-1,1-difluoroethane: Considerations about its molecular nature
โœ G. Huybrechts; G. Van Assche ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 144 KB ๐Ÿ‘ 2 views

A new insight into the contested origin of the absence of radical reaction in the pyrolysis of CF 2 ClCH 3 is given. This chain reaction would be too slow compared with the molecular reaction because of a too slow homogeneous initiation leading to a too fast wall recombination of the Cl atom chain c