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Pyrolysis of 1-chloro-1,1-difluoroethane: Considerations about its molecular nature

✍ Scribed by G. Huybrechts; G. Van Assche

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 144 KB
Volume: 31
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(1999)31:4<283::aid-kin6>3.0.co;2-i

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✦ Synopsis

A new insight into the contested origin of the absence of radical reaction in the pyrolysis of CF 2 ClCH 3 is given. This chain reaction would be too slow compared with the molecular reaction because of a too slow homogeneous initiation leading to a too fast wall recombination of the Cl atom chain carriers.

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The thermal dehydrochlorination has been studied CF ClCH : CF " CH ϩ HCl 2 3 2 2 in a static system between 597 and in the presence of CCl 4 , C 2 Cl 6 , CF 2 "CH 2 , HCl, and 664 K CF 3 CH 3 . A kinetic radical and molecular reaction model has been developed. In addition to describing earlier resul