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Pyrolysis of 2-Pentene and Trimethylethyllene

โœ Scribed by Hepp, H. J.; Frey, F. E.


Book ID
127075845
Publisher
American Chemical Society
Year
1949
Weight
608 KB
Volume
41
Category
Article
ISSN
0019-7866

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H2S-promoted thermal isomerization of ci
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H,S accelerates the thermal isomerization of cis-2-pentene (P2c) to 1-pentene (P1) and trans-2-pentene (P2t) to around 800 K. This effect is interpreted on the basis of a free radical mechanism in which 2-pentenyl and thiyl radicals are the main chain carriers. P1 formation is essentially explained