ISOMERS OF 2-PENTENE. II. PENTENE-2 FROM 2-BROMOPENTANE AND FROM 2-PENTANOL 1
β Scribed by Sherrill, Mary L.; Baldwin, Catherine; Haas, Dorothea
- Book ID
- 127192219
- Publisher
- American Chemical Society
- Year
- 1929
- Tongue
- English
- Weight
- 519 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
H,S accelerates the thermal isomerization of cis-2-pentene (P2c) to 1-pentene (P1) and trans-2-pentene (P2t) to around 800 K. This effect is interpreted on the basis of a free radical mechanism in which 2-pentenyl and thiyl radicals are the main chain carriers. P1 formation is essentially explained
The kinetics of the reactions of ground state oxygen atoms with 1-pentene, 1-hexene, cis-2pentene, and trans-2-pentene was investigated in the temperature range 200 to 370 K. In this range the temperature dependences of the rate constants can be represented by k Ο AΠ T n exp(Οͺ E a Π/RT) with AΠ Ο (1