Pyrolysis and IR laser photolysis of SiH4 molecules in the presence of non reactive and reactive additives
β Scribed by M. Bertolotti; D. Consalvo; A. Mele; A. Giardini-Guidoni; R. Teghil
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 323 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0169-4332
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## Abstract Matrix isolation experiments give evidence for the formation of the loosely bonded metalβsilane complex Mβ SiH~4~ by the spontaneous reaction of Al or Ga atoms (M) with silane in a solid Ar matrix at 12 K; however, Ga~2~ appears to insert spontaneously into an Siο£ΏH bond to form HGaGaSiH~