Pyridine-2,5-dicarboxylic acid complexes of nickel(II) with 2,2′-bipyridine and 1,10-phenanthroline coligands; syntheses, crystal structures, spectroscopic and thermal studies
✍ Scribed by Alper Tolga Çolak; Demet Akduman; Okan Zafer Yeşilel; Orhan Büyükgüngör
- Publisher
- Springer
- Year
- 2009
- Tongue
- English
- Weight
- 473 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0340-4285
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## Reactions of bis(1-oxopyridine-2-thione) Ni II or CH ll with 2,2'-bipyridine (bipy) or 1,10-phenanthroline (phen) yield complexes of stoichiometry: Ni(CsH4NOS)2L {L = bipy, two isomers: (1) and (2), L = phen, one isomer (3)} and Cu(CsH4NOS)2(phen).0.75CHC13 (4). The spectroscopy (i.r., u.v.-vis
## Abstract A mononuclear Cu(II) complex with mixed ligands, formulated as [Cu(hypydc)(dmp)]·H~2~O (hypydc=4‐hydroxypyridine‐2,6‐dicarboxylate, dmp=2,9‐dimethyl‐1,10‐phenanthroline), was synthesized and well characterized by single crystal X‐ray diffraction analysis, as well as spectroscopic (IR, U