Pyramidal Inversion in Cyclic Sulfonium Salts
β Scribed by A. Garbesi; N. Corsi; A. Fava
- Book ID
- 102252053
- Publisher
- John Wiley and Sons
- Year
- 1970
- Tongue
- German
- Weight
- 297 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Recently Fava and Koch (1) concluded that aryl arenethiolsulfinates readily undergo thermal racemization via pyramidal inversion at sulfinyl sulfur.
Polymers are produced by direct photolysis of substituted aryl cyclic sulfonium Zwitterionic salts in solution or film. Analysis of zwitterionic monomers via 13 C NMR, UV, and IR spectroscopy as well as X-ray diffraction clearly identifies the structures taking part in the photoinduced polymerizatio
Thermal racemisation of optically active sulfonium salts may proceed by three routes: pyramidal inversion (A.), dissociation by a SN1 mechanism (z), or dissociation by a SN2 (2) mechanism: R2RsS + R:(X ) ?.