๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Absence of pyramidal inversion in a cyclic thiolsulfinate

โœ Scribed by Fred Wudl; Robert Gruber; Albert Padwa

Book ID
104239430
Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
194 KB
Volume
10
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

โœฆ Synopsis

Recently Fava and Koch (1) concluded that aryl arenethiolsulfinates readily undergo thermal racemization via pyramidal inversion at sulfinyl sulfur.

๐Ÿ“œ SIMILAR VOLUMES

Direct determination of the absolute con
Direct determination of the absolute configuration of a cyclic thiolsulfinate by VCD spectroscopy
โœ Anders Holmรฉn; Joakim Oxelbark; Stig Allenmark ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 137 KB

Experimental and calculated vibrational circular dichroism (VCD) spectra of the enantiomers of the conformationally rigid thiolsulfinate, naphtho[1,8-cd]-1,2-dithiole 1-oxide 1, obtained by chromatographic resolution of the racemate, were in excellent agreement, showing a (+)-(S)-1/(-)-(R)-1 relatio