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Pyramidal inversion barriers and linear free energy relationships

✍ Scribed by Joseph Stackhouse; Raymond D. Baechler; Kurt Mislow

Book ID
104248127
Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
203 KB
Volume
12
Category
Article
ISSN
0040-4039

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✦ Synopsis

It has bean recognized that Raraeett type free energy relationships rney be usefully applied to the process of pyramidal inversion. The first such application dealt with the racemization of sulfoxides (l), and similar treatments have appeared for phosphine (2) and aziridine (3) systems.

Linear log k/log k' plots have been obtained (2,3) for pphenyl substituted compounds which serve

πŸ“œ SIMILAR VOLUMES

The relationship of barrier shape to β€œli
The relationship of barrier shape to β€œlinear” free energy slopes and curvatures
✍ Joseph L. Kurz πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 English βš– 405 KB

LeffIer's interpretation of linear free energy slopes is derivable from a general set of symmetric barrier functions. Marcus' rate equation is derivable from a subset of those barriers which includes E&art's barrier.