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Putting tert-Butyl Cation in a Bottle

✍ Scribed by Tsuyoshi Kato; Christopher A. Reed


Book ID
101567350
Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
246 KB
Volume
43
Category
Article
ISSN
0044-8249

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Treatment of either 2-tert-butyl-2-adamantanol or 2-lsopropenyl-2-methyladamantane with acid in the presence of a reducing agent (hydrogen iodide or tn-c-hexylsllane) yielded 2-tert-butyladamantane as the maJor or exclusive product buw2-adamantyl cation at -78Β°C in FS03H-SbF5-S02ClF