𝔖 Bobbio Scriptorium
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Purification of sodium and potassium hydrides; preparation of trialkylborohydrides with exceptionally large steric requirements

✍ Scribed by John L. Hubbard

Book ID
107858408
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
230 KB
Volume
29
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Addition compounds of alkali metal hydri
Addition compounds of alkali metal hydridesβ€”XIX: Rapid reaction of trialkylboranes with lithium aluminum hydride in the presence of triethylene-diamine. A facile and quantitative synthesis of lithium trialkylborohydrides, including derivatives with exceptionally large steric requirements
✍ Herbert C. Brown; John L. Hubbard; Bakthan Singaram πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 403 KB

Abdrad-Trialkylborancs react rapidly with lithium aluminium hydride (LAH) in dicthyl ether in the presence of triethykncdiamim (TED) at 0" to form the corresponding lithium triakylborohydrides and aluminum hydride. The aluminum hydride precipitates out of solution as its triethylenediamine adduct. T