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Purification of Biomass-Derived 5-Hydroxymethylfurfural and Its Catalytic Conversion to 2,5-Furandicarboxylic Acid

✍ Scribed by Yi, Guangshun; Teong, Siew Ping; Li, Xiukai; Zhang, Yugen

Book ID
121875197
Publisher
Wiley (John Wiley & Sons)
Year
2014
Tongue
English
Weight
672 KB
Volume
7
Category
Article
ISSN
1864-5631

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On the mechanism of selective oxidation
On the mechanism of selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over supported Pt and Au catalysts
✍ Davis, Sara E. ;Zope, Bhushan N. ;Davis, Robert J. πŸ“‚ Article πŸ“… 2012 πŸ› Royal Society of Chemistry 🌐 English βš– 411 KB

The mechanism of selective oxidation of aqueous 5-hydroxymethylfurfural (HMF) at high pH was studied over supported Pt and Au catalysts. Results from labeling experiments conducted with 18 O 2 and H 2 18 O indicated that water was the source of oxygen atoms during the oxidation of HMF to 2-hydroxyme