𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Pummerer reaction in sulfoxides of the sulfolane series

✍ Scribed by N. N. Novitskaya; B. V. Flekhter; L. V. Spirikhin; G. A. Tolstikov

Book ID
112326531
Publisher
Springer US
Year
1979
Tongue
English
Weight
41 KB
Volume
15
Category
Article
ISSN
0009-3122

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Unusually high asymmetric induction in t
Unusually high asymmetric induction in the pummerer reaction of opticaly active sulfoxides
✍ Tatsuo Numata; Osamu Itoh; Shigeru Oae πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 French βš– 128 KB

The Pummerer reaction of optically active B-carbonyl substituted alkyl sulfoxides with acetic anhydride in the presence of dicyclohexylcarbodiimide was found to be of highly stereoselective affording the corresponding a-acetoxysulfides with nearly 70% e.e. Among several examples of stereoselective P

ChemInform Abstract: New Reactions of Cy
ChemInform Abstract: New Reactions of Cyclic Sulfoxides under Pummerer Conditions.
✍ R. Alan Aitken; Lawrence Hill; Philip Lightfoot; Neil J. Wilson πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 30 KB πŸ‘ 1 views

All attempts to convert compound (I) into (VI) fail. It is noteworthy that also DDQ reacts with (I) to give (III) in 37% yield. The structure of (III) is determined by X-ray analysis. Mechanistical aspects are discussed. -