The 7 Li 2 5 1 + g and 6 1 + g states have been studied both experimentally and theoretically. Vibrational levels v = 1-26 of the 5 1 + g state and v = 2-14 of the 6 1 + g state were observed using pulsed optical-optical double resonance technique. The 5 1 + g state has an unusual potential energy c
Pulsed PFOODR Spectroscopy of Triplet Rydberg States of 7Li2
โ Scribed by D.S. Chen; L. Li; X.T. Wang; L. Li; Q. Hui; H. Ma; L.Q. Li; X.Y. Xu; D.Y. Chun
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 389 KB
- Volume
- 161
- Category
- Article
- ISSN
- 0022-2852
No coin nor oath required. For personal study only.
โฆ Synopsis
The triplet (\mathrm{R}) ydberg states of ({ }^{7} \mathrm{Li}{2}) have been studied by pulsed perturbation facilitated opticaloptical double resonance (PFOODR) fluorescence excitation spectroscopy via three mixed (A^{1} \Sigma{u}^{+} \sim b^{3} \Pi_{u}) intermediate levels. Twenty-one vibrational levels of the (2^{3} \Pi_{\mathrm{g}}) state, 6 vibrational levels of the (1^{3} \Delta_{\mathrm{g}}) state, and more than 40 PFOODR transitions into other triplet Rydberg states have been observed. Molecular constants and the RKR potential energy curve of the ({ }^{7} \mathrm{Li}{2} 2^{3} \Pi{\mathrm{g}}) state have been obtained. ยฉ 1993 Academic Press, Inc.
๐ SIMILAR VOLUMES
The effect on the solid-state 'Li chemical shifts and quadrupolar coupling constants of different locations of the lithium cation relative to the carbanion framework of delocalized carbanions was investigated. When the lithium cation is situated above the conjugated system, the chemical shift is abo
The wavelength-resolved fluorescence excitation technique has been used to record the \((0,0)\) bands of the satellite \(e^{3} \Pi_{1}-a^{3} \Delta_{1}\) and \(e^{3} \Pi_{2}-a^{3} \Delta_{2}\) transitions of ZrO at a resolution of \(0.03 \mathrm{~cm}^{-1}\). These data were combined with previous hi
The predissociation of the 1 3 โบ g ฯช v ี 10 levels of 7 Li 2 has been observed by pulsed and continuous-wave perturbationfacilitated optical-optical double-resonance spectroscopy (PFOODR). Our ab initio calculation shows that the inner wall of the 1 3 โบ g ฯช potential intersects the 1 3 โธ g repulsive