Real-time kinetic measurements are reported for the Cl ϩ CH 3 CO : CH 2 CO ϩ HCl reaction. The experiments utilize infrared spectroscopy to determine the time dependence of the ketene formed via this reaction and of the CO produced from the subsequent rapid reaction between chlorine atoms and ketene
Pulsed laser photolysis study of the reaction Cl+FSO3+M→FSO2OCl+M
✍ Scribed by A.E. Croce; C.J. Cobos; E. Castellano
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 371 KB
- Volume
- 158
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The exothermic abstraction reactions Ba + R-Cl (R = o-, m-and pC6H4Cl) have been studied using the laser-induced fluorescence method in a beam-gas arrangement. A modified statistical model based on Marcus has been proposed to calculate the distributions of internal energy states of the product molec
The photolysis of phenylazotriphenyl methane (PAT) in dichloromethane and acetonitrile solution at and at 23¡C results in the j inc \ 347 nm formation of triphenyl methyl (trityl) radicals and trityl ions. The quantum yields in dichloromethane solution are and Trityl '(Ph ions are assumed to be for
A laser flash photolysis study of the photoinduced electron-transfer reaction between pyrene and indole is reported. The pyrene radical anion and the hydropyrenil radical were confirmed as reaction intermediates from their transient absorption spectra. The photobleaching of pyrene was observed in th