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Non-linear absorption and photoionization in the pulsed laser photolysis of anthracene

✍ Scribed by Michael M. Fisher; Bernard Veyret; Karl Weiss

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
802 KB
Volume
28
Category
Article
ISSN
0009-2614

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Falloff curves for the unimolecular deco
Falloff curves for the unimolecular decomposition of two acyl radicals: RCO (+M) β†’ R + CO (+M) by pulsed laser photolysis coupled to time-resolved infrared diode laser absorption
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## Abstract The rate constants __k__~d~ for the unimolecular decomposition of two acyl (RĊO) radi‐ cals: 2,2‐dimethylpropionyl (CH~3~)~3~CĊO and 2‐methylpropionyl (CH~3~)~2~CHĊO (pivaloyl and isobutyryl, respectively in what follows) have been directly measured via the time‐resolved kinetics of CO