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Pulse radiolytic studies of the reaction of pentahalophenols with OH radicals: formation of pentahalophenoxyl, dihydroxypentahalocyclohexadienyl, and semiquinone radicals

✍ Scribed by Terzian, Rita.; Serpone, Nick.; Draper, R. Barton.; Fox, Marye Anne.; Pelizzetti, Ezio.


Book ID
118029441
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
971 KB
Volume
7
Category
Article
ISSN
0743-7463

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Replacement of N 2 by CO in H 2 + 02 + N 2 mixtures undergoing slow reaction at 500Β°C causes a marked increase in the reaction rate and a decrease in the induction period, expressed as the time to half maximum rate. A detailed interpretation using a computer treatment gives k24/klo 1/2 = 0.42 Β± 0.03