Pt2(HSO4)2(SO4)2, the First Binary Sulfate of Platinum.
β Scribed by Martin Pley; Mathias S. Wickleder
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 19 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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Synthesis and Crystal Structure of Metal(I) Hydrogen Sulfates -Ag(H 3 O)(HSO 4 ) 2 , Ag 2 (HSO 4 ) 2 (H 2 SO 4 ), AgHSO 4 , and Hg 2 (HSO 4 ) 2 . -The silver hydrogen sulfates of title are synthesized from Ag 2 SO 4 in hot conc. H 2 SO 4 . Hg 2 (HSO 4 ) 2 is obtained from metallic Hg in conc. H 2 S
Inhaltsu Γ bersicht. Aus einer Lo Γ sung von Er 2 (SO 4 ) 3 in konz. H 2 SO 4 kristallisiert bei 250 Β°C Er(HSO 4 ) 3 -I (orthorhombisch, Pbca, a = 1195,0(1) pm, b = 949,30(7) pm, c = 1644,3(1) pm) in Form hellrosa sa Γ uliger Kristalle. Aus 85%iger H 2 SO 4 -Lo Γ sung, der Na 2 SO 4 zugesetzt wurde,