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Pseudorotation in Radical Cations of Low-Symmetric Decalin Molecules

✍ Scribed by Beregovaya, Irina V.; Shchegoleva, Lyudmila N.; Borovkov, Vsevolod I.

Book ID
111875417
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
136 KB
Volume
113
Category
Article
ISSN
1089-5639

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πŸ“œ SIMILAR VOLUMES

Electronic states of cis- and trans-deca
Electronic states of cis- and trans-decalin radical cations in zeolites
✍ Mary V. Barnabas; Alexander D. Trifunac πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 English βš– 494 KB

The radical cations ofcis-and transdecalin have been studied in different synthetic zeolite matrices by EPR spectroscopy. The radical cations were produced by y-radiolysis at 77 K. The tirst experimental observation of both the electronic states (2Al : a(4H)=50 G and \*A$ a(4H)=29 G) of the cis-deca

Ionβ€”molecule reactions of tetramethyleth
Ionβ€”molecule reactions of tetramethylethylene radical cations in zeolites
✍ Mary V. Barnabas; Alexander D. Trifunac πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 588 KB

Radical cations were produced by y-irradiation of solutes in zeolites at 77 K. The radical cation of tetramethylethylene (TME) was examined by EPR in a variety of zeolites at different temperatures and loading. The TME monomer radical cation, the TME dimer radical cation and the neutral radical form