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MARY and Optically Detected ESR Spectroscopy of Radical Cations of cis- and trans- Decalin in Nonpolar Solutions

✍ Scribed by Tadjikov, Boris M.; Stass, Dmitrii V.; Molin, Yuri N.


Book ID
127049562
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
173 KB
Volume
101
Category
Article
ISSN
1089-5639

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πŸ“œ SIMILAR VOLUMES


Electronic states of cis- and trans-deca
✍ Mary V. Barnabas; Alexander D. Trifunac πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 English βš– 494 KB

The radical cations ofcis-and transdecalin have been studied in different synthetic zeolite matrices by EPR spectroscopy. The radical cations were produced by y-radiolysis at 77 K. The tirst experimental observation of both the electronic states (2Al : a(4H)=50 G and \*A$ a(4H)=29 G) of the cis-deca

The electronic structure of cis- and tra
✍ V.I. Melekhov; O.A. Anisimov; L. SjΓΆqvist; A. Lund πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 English βš– 642 KB

The ESR spectra of radical cations of cis-and trans-deealin have been recorded in different halocarbon matrices within the temperature range 4.2 IO 130 K. The ground-state structures of both isomers have been calculated using the UHF/MNDO technique and found to be 'As or ZB, for transdecalin+ and 'A

Can both cis- and trans-isomers of the 9
✍ Brian P. Roberts; Andrew J. Steel πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 French βš– 290 KB

A ptevrous report that distinguishable ESR spectra can be obtained from CIS-and truns-Isomers of the 9-decalyl radical m liquid solution at low temperature is shown to be incorrect. Only one spectrum, assigned to the rrans-radtcal, is observable from etther CIS-or rruns-precursors In 1985 Lloyd and