✦ LIBER ✦

Pseudorotation and the environmental effects of the phosphorescence lifetime of benzene

✍ Scribed by S Fischer

Publisher: Elsevier Science
Year: 1971
Tongue: English
Weight: 559 KB
Volume: 10
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(71)80318-4

No coin nor oath required. For personal study only.

✦ Synopsis

The strong temperature dependence of the phosphorescent decay rate of benzene is at&ii&e& to pseudorotational motion of benzene which hk the lowered DZJ, symmetry in the triplet state. This mod@ ZUXOKI+ for the unusual deuteriun effect of the activation energy, the,very large pre-exponential factor, the low onset tqwratwe, ami the sohmlt effects.

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