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Pseudo-Geminally-Substituted [2.2]Paracyclophanes as Spacers for Bisallenyl Sulfoxides and Sulfones.

โœ Scribed by M. Lucian Birsa; Peter G. Jones; Samuel Braverman; Henning Hopf


Publisher
John Wiley and Sons
Year
2005
Weight
18 KB
Volume
36
Category
Article
ISSN
0931-7597

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## Abstract Synthetic routes to __pseudoโ€geminal__, __pseudoโ€ortho__ and __ortho__ hydroxyโ€oxazolinyl[2.2]paracyclophanes (and the diastereoisomers of each) for use as N,O ligands in asymmetric catalysis have been devised. The substitution pattern was found to have a strong effect on the rate and e