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Proximity Effects. XI. Reaction of trans-1,2-Dibromocycloheptane with Silver Acetate 1

✍ Scribed by Cope, Arthur C.; Acton, Edward M.; Johnson, Herbert E.; Wood, Geoffrey W.

Book ID: 126040941
Publisher: American Chemical Society
Year: 1957
Tongue: English
Weight: 533 KB
Volume: 79
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01580a048

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In previous studies on the stereochemistry of benzyne addition to enol ethers and acetates we observed both stereoselective 2+2 cycloaddition and ene reaction. 1 In each series, however, we found that the proportion of ene product relative to cycloaddition was significantly larger with the trans-is