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Protonation of polyaniline with lightly sulfonated polystyrene

✍ Scribed by Yueping Fu; R. A. Weiss


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
337 KB
Volume
17
Category
Article
ISSN
1022-1336

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✦ Synopsis


Abstract

Protonation of polyaniline base with lightly sulfonated polystyrene in polar solvents such as dimethyl sulfoxide and N‐methyl‐2‐pyrrolidone was investigated by UV‐Vis absorption spectra. As the molar ratio of sulfonated polystyrene/polyaniline increases, the conversion from polyaniline base form to salt form is observed owing to increased protonation. The isosbestic point clearly shows that quinoid unit and semiquinoid unit are in equilibrium. They are functions of the sulfonic acid concentration and solvent media.


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