Protonation of N,N',N''-triphenyl-1,3,5-triaminobenzenes: stable .sigma.-complexes
โ Scribed by Glatzhofer, Daniel T.; Allen, Derrick; Taylor, Richard W.
- Book ID
- 126124296
- Publisher
- American Chemical Society
- Year
- 1990
- Tongue
- English
- Weight
- 403 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
Correlation analysis of the oxidation potentials of a series of N,N',N@-triphenyl-1,3,5-triaminobenzenes (TPABs) substituted at the para positions of the outer phenyl rings shows a linear free energy relationship with resonance-enhanced substituent parameters (s ). Reaction parameters (r ) for oxida
Nitric oxide (NO), nitroxyl (HNO), and hydroxylamine have been invoked as key intermediates in the biological multielectron reduction of nitrite to ammonia, which is a fundamental process in the inorganic nitrogen cycle in nature. The reaction is catalyzed by a certain type of nitrite reductase that