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N-Methylhydroxylamido(1−)- and Nitrosomethaneruthenium Complexes Derived from Nitrosyl Complexes: Reversible N-Protonation of an N-Coordinated Nitrosoalkane

✍ Scribed by Satoshi Kura; Shigeki Kuwata; Takao Ikariya

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
126 KB
Volume
44
Category
Article
ISSN
0044-8249

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✦ Synopsis

Nitric oxide (NO), nitroxyl (HNO), and hydroxylamine have been invoked as key intermediates in the biological multielectron reduction of nitrite to ammonia, which is a fundamental process in the inorganic nitrogen cycle in nature. The reaction is catalyzed by a certain type of nitrite reductase that contains heme moieties at its active site.

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