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Protonation of 18-crown-6 by dichloropicric acid in anhydrous and in water saturated 1,2-dichloroethane. Homoconjugation of dichloropicric acid

✍ Scribed by Miran K. Chantooni; Izaak M. Kolthoff


Book ID
104864018
Publisher
Springer US
Year
1992
Tongue
English
Weight
647 KB
Volume
21
Category
Article
ISSN
0095-9782

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6-(Triphenylphosphonio-3Ј-cyclopentadienyl)-2,3,5-trihalocyclohexa-2,5-diene-1,4-diones (2) are a new class of phosphorus containing dyes that behave as weak bases. Mono-protonation occurs at the cyclopentadiene ring leading to three isomers as assessed by NMR. The kinetics of the protonation were s