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Protonation and Alkylation of the Thiolato Donors in [Fe(CO)(“NHS4”)]: Effects on the Structural, Electronic, and Redox Properties of Metal–Sulfur Complexes

✍ Scribed by Prof. Dr. Dieter Sellmann; Dr. Thomas Becker; Dr. Falk Knoch


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
732 KB
Volume
2
Category
Article
ISSN
0947-6539

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✍ Jens Wolff, J. ;Gredel, Frank ;Hillenbrand, Daniela ;Irngartinger, Hermann 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 832 KB

## Abstract The conformational properties of triamino‐substituted 1,3,5‐trinitrobenzenes were studied by X‐ray crystallography, dynamic NMR spectroscopy, and semiempirical calculations. As amino substituents all possible combinations of a dialkyl‐, a monoalkylamino, and an amino group were used. Al