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Protonated Sulfuric Acid: Preparation of Trihydroxyoxosulfonium Hexafluoroantimonate H3SO4+SbF6−

✍ Scribed by Rolf Minkwitz; Raphael Seelbinder; René Schöbel


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
172 KB
Volume
41
Category
Article
ISSN
0044-8249

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The Protonation of CF3SO3H: Preparation
✍ Theresa Soltner; Nadine R. Goetz; Andreas Kornath 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 460 KB 👁 1 views

Trifluoromethanesulfonic anhydride reacts with superacidic solutions AF/SbF 5 (A = H, D) to form their corresponding salts CF 3 SO 3 A 2 + SbF 6 -, which are protonated forms of trifluoromethanesulfonic acid and CF 3 SO 2 F as by-product. The salts have been characterized by vibrational spectroscopy