Proton transfer reaction of 4-hydroxy-1-naphthalenesulphonate in methanol-water and ethanol-water mixtures
โ Scribed by M. Than Htun; A. Suwaiyan; Uwe K.A. Klein
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 498 KB
- Volume
- 243
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
## Abstract The title reaction was studied in different waterโcosolvent (methanol) mixtures. The results have been rationalized employing the MarcusโHush treatment. To apply this treatment, the true, unimolecular, electronโtransfer rate constants (__k__~et~) were obtained from the experimentally me
## ยจq ยจy where M and X indicate electrodes reversible to the cation M zq and to the anion X zy , respectively, M zq X zy is the corresponding general strong binary electrolyte ยจq ยจy at molality m, and Z is a binary aqueous-organic solvent mixture, is of key importance not only to electrochemists b
For the solvolysis of Co(4-t-Bupy)rClz-ions in water + methanol and water + ethanol, log (rate constant) does not vary linearly with the reciprocal of the dielectric constant. The Gibbs free energy, the enthalpy, and the entropy of activation are insensitive to changes in the solvent composition in