Proton radiolysis of carbon dioxide
โ Scribed by Anderson, A. R.; Best, J. V. F.
- Book ID
- 121470589
- Publisher
- Royal Society of Chemistry
- Year
- 1966
- Weight
- 786 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0014-7672
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๐ SIMILAR VOLUMES
The self-radiolysis of COZ in excess tritium (3Hz) has been studied at pressures of 0.1 to 1.0 atm, temperatures of -80' to +lOO"C, and in the presence of added HzO, He, or Ar. The primary products of decomposition are C O and 3Hz0. Secondary products are C3H4, CzaH4, and a white polymer. The rates
Equilibrium structures of protonated carbon dioxide are explored by ab initio molecular orbital theory. The hydroxyearbonyl cation (I) is found to be most stable; the associated proton affinity is calculated to be 130 kcal/rnol, in reasonable agreement withexperimental data. The dioxiryl cation (IV&