Preparation and Structural Investigations of (dippNSiMe 3 Si) 2 (Cp\*Ti) 2 (NH) 6 (dipp ؍ 2,6-iPr 2 C 6 H 3 ), [dippNSiMe 3 Si(NH
Proton NMR Spectroscopy Investigation of the (C4H9NH3)2SnCl6 and (C12H25NH3)2SnCl6 Hexachlorostannates
✍ Scribed by H. Elleuch; M. Kamoun; A. Daoud; J. M. Reau; J. Sénégas
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 301 KB
- Volume
- 214
- Category
- Article
- ISSN
- 0370-1972
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The title compound has been synthesised, and characterised by multinuclear magnetic resonance spectroscopy, both in solution and in the solid state. The bandshapes of variabletemperature solution-state 19 F NMR spectra have been iteratively fitted to obtain information on the kinetics of rotation ab
Treating [Cp\*V(l-Cl) 2 ] 3 (Cp\* = C 5 Me 5 ) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoMe 2 ], respectively, with Me 3 SnF afforded the title compounds [Cp\*V(l-F) 2 ] 4 (1) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoF 2 ] ´THF ( 2). 1 has a tetrameric structure, in which four V atoms can be regarded as being arranged
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