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Proton NMR Spectroscopy and Magnetic Properties of a Solution-Stable Dicopper(II) Complex Bearing a Single μ-Hydroxo Bridge

✍ Scribed by Koval, Iryna A.; van der Schilden, Karlijn; Schuitema, Anna Maria; Gamez, Patrick; Belle, Catherine; Pierre, Jean-Louis; Lüken, Matthias; Krebs, Bernt; Roubeau, Olivier; Reedijk, Jan

Book ID
120931629
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
256 KB
Volume
44
Category
Article
ISSN
0020-1669

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📜 SIMILAR VOLUMES

μ-η1:η1-N,N'-Imidazolidine-Bridged Dicop
μ-η1:η1-N,N'-Imidazolidine-Bridged Dicopper(II/III) Complexes of a New Dinucleating μ-Bis(tetradentate) Schiff Base Ligand: Synthesis, Structural Characterization, 1H NMR Spectroscopy, and Magnetic Coupling
✍ Manindranath Bera; Wing Tak Wong; Guillem Aromí; Debashis Ray 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 209 KB 👁 1 views

## Abstract The copper coordination chemistry of a new imidazolidine‐based doubly bridging μ‐bis(tetradentate) ligand, H~3~mhbai is studied. A new family of pentacoordinate dinuclear complexes of formula [Cu^II^~2~(‐mhbai)(‐X)]·2 H~2~O (1–4) [X = OAc, NO~3~, Cl, S~2~COMe], where H~3~mhbai stands fo