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Proton magnetic resonance spectra of ethylene episulfoxides. Anomaly in magnitudes of spin-coupling constants between ring protons

✍ Scribed by M. Ohtsuru; K. Tori; M. Fukuyama


Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
175 KB
Volume
11
Category
Article
ISSN
0040-4039

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✦ Synopsis


In the course of the chemical study of episulfoxides (I, 2), we hove found in the PMR spectm of ethylene episulfoxide (I)*3 and propylene episulfoxide (II) that the J-values between ring protons are abnormal in comparison with those obtained in other three-membered heterocyclic compounds.


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High-resolution proton spectra of acridine and the five monomethyl derivatives have been analyzed using multiple resonance and computer techniques. It was possible to determine the magnitudes and relative signs of the inter-ring coupling constants between H-C( 9) and all the protons of the adjacent