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Proton exchange in the lowest excited singlet state of 2-naphthol-6,8-disulfonate. Demonstration of the establishment of prototropic equilibrium in the excited state

โœ Scribed by Schulman, Stephen G.; Rosenberg, Leonard S.; Vincent, William R.


Book ID
126106421
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
466 KB
Volume
101
Category
Article
ISSN
0002-7863

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Establishment of prototropic equilibrium
โœ Brian S. Vogt; Stephen G. Schulman ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 308 KB

In concentrated sulfuric acid (==5 M), the proton-transfer reaction of 1-isoquinolone attains equilibrium within the liietime of the excited state. One consequence is that our knowledge of the role of tvater in the reaction is limited