PPP cnIcul&ion$ on I-arylbutadlcnes prcdlct il forblddcn transition slightly below the first allowed transition. The two lowest cxltcd Gngiet states have different cAxMed charge dcnsttics, implying different types of photochemical reaction.
โฆ LIBER โฆ
Establishment of prototropic equilibrium in the lowest excited singlet state of 1-isoquinolone
โ Scribed by Brian S. Vogt; Stephen G. Schulman
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 308 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
In concentrated sulfuric acid (==5 M), the proton-transfer reaction of 1-isoquinolone attains equilibrium within the liietime of the excited state. One consequence is that our knowledge of the role of tvater in the reaction is limited
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