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Proton-controlled nitroxide mediated radical polymerization of styrene

✍ Scribed by Yann Le Du; Laurent Binet; Patrick Hémery; Lucien Marx

Book ID
112175659
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
961 KB
Volume
50
Category
Article
ISSN
0887-624X

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## Abstract The nitroxide‐mediated controlled radical polymerization (NM‐CRP) of 4‐acetoxystyrene with an alkoxyamine was analyzed by a combined experimental and modeling approach. At low nitroxide concentrations, thermal initiation was significant, and control of the polydispersity was poor, as wa