Nitroxide-Mediated Controlled Radical Styrene Polymerization Via a Mass-Suspension Process
✍ Scribed by García-Leal, Enrique; Ordaz-Quintero, María Almendra; Saldívar-Guerra, Enrique; Albores-Velasco, Martha Eugenia; Vivaldo-Lima, Eduardo
- Book ID
- 120936408
- Publisher
- John Wiley and Sons
- Year
- 2013
- Tongue
- English
- Weight
- 747 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1862-832X
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## Abstract The nitroxide‐mediated controlled radical polymerization (NM‐CRP) of 4‐acetoxystyrene with an alkoxyamine was analyzed by a combined experimental and modeling approach. At low nitroxide concentrations, thermal initiation was significant, and control of the polydispersity was poor, as wa
## Abstract **Summary:** A semi‐batch process using nitroxide mediated polymerization, was explored for the design of low molecular weight solvent‐borne coatings, typical of those used in the automotive industry. While living radical polymerization (LRP) offers many advantages in the control of pol