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Proton affinity of phosphoryl compounds and σΦ-substituent constants

✍ Scribed by L. N. Alekseiko; V. V. Gorchakov; M. I. Kabachnik; E. I. Matrosov; S. N. Slabzhennikov


Book ID
112448830
Publisher
Springer
Year
1991
Tongue
English
Weight
297 KB
Volume
40
Category
Article
ISSN
1573-9171

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The change in the proton affinity (PA) and basicity (GB) of pyridine with substituents have been considered by quantum mechanical methods at the B3LYP/6-311++G(d,p) level of theory. The PA and GB values increase by the electron-donating substituents and decrease by the electron-withdrawing substitue