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Protolytic opening of the furan ring in the synthesis of 5H,10H-dipyrrolo[1,2-a:1',2'-d]pyrazines

✍ Scribed by T. A. Nevolina, V. A. Shcherbinin, P. M. Shpuntov, A. V. Butin

Book ID
118298126
Publisher
Springer US
Year
2012
Tongue
English
Weight
266 KB
Volume
48
Category
Article
ISSN
0009-3122

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## Abstract The dipyrroloimidazolyl ligand is found to bind the pentacarbonylmanganese group to its central ring __via__ a carbon‐metal σ‐bond. This bonding mode differs greatly from that of known imidazole complexes and from the pentahapto mode encountered with the isoelectronic fluorenyl ligand.