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Protodemetallation reactions of some diphenylthallium(III) compounds with dicyclohexyldithiophosphinic acid. Crystal and molecular structures of [TlPh2{S2P(C6H11)2}], [TlPh{S2P(C6H11)2}2] and [Tl{S2P(C6H11)2}3]�CHCl3

✍ Scribed by Casas, Jos� S.; Castellano, Eduardo E.; Casti�eiras, Alfonso; S�nchez, Agust�n; Sordo, Jos�; V�zquez-L�pez, Ezequiel M.; Zukerman-Schpector, Julio


Book ID
120248059
Publisher
The Royal Society of Chemistry
Year
1995
Tongue
English
Weight
929 KB
Volume
9
Category
Article
ISSN
1472-7773

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Reaction of trans-{PtH2[P(C6H11)3]2} wit
✍ A. Albinati; A. Musco; G. Carturan; G. Strukul 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 427 KB

## Carbon disulphide inserts into the Pt-H bond oj trans-{PtH,[P(C~,1)3]2} to give trans-{PtH(S,CH) [P(CJ113J2}. The X-ray structure shows that the -S2CH group is bonded to the metal through a sulfur atom as a monodentate thioformate anion. The kinetics of the carbon disulfide insertion have been in