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Nucleophilic attack on {(π-ally)Pt[P(C6H11)3]2}PF6. Preparation and X-ray structure of trans-{PtH2[P(C6H11)3]2}

✍ Scribed by A. Immirzi; A. Musco; G. Carturan; U. Belluco

Book ID
114040895
Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
141 KB
Volume
12
Category
Article
ISSN
0020-1693

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Reaction of trans-{PtH2[P(C6H11)3]2} wit
Reaction of trans-{PtH2[P(C6H11)3]2} with carbon disulphide. Kinetic study of the insertion reaction and X-ray structure of trans-{PtH(S2CH)[P(C6H11)3]2}
✍ A. Albinati; A. Musco; G. Carturan; G. Strukul 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 427 KB

## Carbon disulphide inserts into the Pt-H bond oj trans-{PtH,[P(C~,1)3]2} to give trans-{PtH(S,CH) [P(CJ113J2}. The X-ray structure shows that the -S2CH group is bonded to the metal through a sulfur atom as a monodentate thioformate anion. The kinetics of the carbon disulfide insertion have been in