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Preparation and X-ray structure of a platinum(II) hydroxycarbonyl, Pt(CO2H){C6H3(CH2PPh2) 2-2,6}, containing a trans-spanning, tridentate P,C,P-ligand

โœ Scribed by Martin A. Bennett; Hong Jin; Anthony C. Willis


Book ID
107812498
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
835 KB
Volume
451
Category
Article
ISSN
0022-328X

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The tetrakis(phosphane oxide) C 6 H 2 {CH 2 P(O)Ph 2 } 4 -1,2,4,5 (5), has been prepared in high yield from the Arbuzov reaction of C 6 H 2 (CH 2 Br) 4 -1,2,4,5 (4), with excess (7 equiv.) of Ph 2 POEt. Subsequent reduction of 5 with HSiCl 3 (12 equiv.) in C 6 H 4 Cl 2 -1,2 afforded the new tetrapho