Protodemercuration of some mercury derivatives of ferrocene and cyclopentadienylmanganese tricarbonyl
โ Scribed by A.N. Nesmeyanov; E.G. Perevalova; S.P. Gubin; A.G. Kozlovskii
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- English
- Weight
- 780 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
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## Abstract Eight novel methylcarbamates, derivatives of ferrocenylketoximes and aldoximes, and ferrocenylโpโhydroxyphenylaldimine were prepared. They are the first carbamates in the field of ferrocene derivaties. Their anticholinesterase activity was tested and found to fall in the range of 10^โ4^
The behaviour of some mono-and di-substituted ferrocene compounds under electron impact has been investigated by means of low-resolution mass spectrometry. Some characteristic rearrangement processes have been observed and discussed.
## Abstract Fifteen ferrocene derivatives IโIX (four of which have been prepared for the first time: II, IIIf, V and VIII) have been prepared by FriedelโCrafts acetylation, Claisen condensation, Michael reaction, and ring closure by hydrazine hydrate. The anodic behaviour of these compounds has bee