Protection of primary and secondary amines in the hydroboration reaction
โ Scribed by A. Dicko; M. Montury; M. Baboulene
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- French
- Weight
- 256 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
Compounds containing both primary and secondary amine moieties in the same molecule were treated sequentially with two equivalents of n-butyllithium at room temperature, two equivalents of TMSCI, one equivalent of nbutyllithium and one equivalent of benzoyl chloride, to afford mono-benzoylated diami
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The kinetics of the reactions of primary and secondary amines with benzhydrylium ions and quinone methides in acetonitrile have been studied under pseudo-first-order conditions (high excess of amines) by UV/Vis spectrophotometry. Generally, the plots of k obs versus amine concentration were linear,